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7th principle of green chemistry
Use of renewable feedstocks: A raw material or feedstock should be renewable rather than depleting whenever
technically and economically practicable.
A feedstock is considered green if it satisfies the following conditions:
• It should impose least demands on the earth's resources.
• It‘s acquisition and refining should be safe.
• It should be non-hazardous and relatively safe.
• If possible, feedstock should always be renewable for example feedstocks from biomass that can be grown
repeatedly should be given preference to depletable petroleum feedstocks.
• Reusing of waste from bio-industries, if possible, as raw material or feedstock. Various examples are listed
below:
1. Chitan, a waste from of seafood industry can be transformed into Chitosan by Deacetylation that has many
applications as in water purification, biomedical and in other industries. It would definitely replace the
petroleum feedstocks.
2. Lignin, a waste from paper and pulp industry, is used as feedstock for manufacture of Annelyn venelin DMSO
Continued….
3. Lipids and hydrocarbon terpenes are the oils, greases and waxes which have same
properties as that of petroleum products and are used to synthesize the synthetic liquid fuels
and also can be used directly as diesel fuel.
4. For chemical synthesis, the fatty acids from natural sources is advantageous because of
the carboxylic acid group and the presence of reactive double bond between two carbon
atoms in the carbon chain. For example oleic acid from sunflower, linolenic acid from soya
bean and linseed, rinoleic acid from Castor oil etc.
5. The carbohydrates as feedstocks have advantages as they have many hydroxyl functional
groups that may provide sites for the attachment of other functionalities or to initiate
chemical reactions.
6. Cellulose another bio feedstock is mostly employed as plant biomass suppliants thus
diminishing the need of petroleum feed stocks.
Biological processes
Biological processes produce a variety of biopolymers like cellulose. hemicellulose,
lignin, starch, proteins, lipids, monosaccharides (glucose), disaccharides (sucrose),
waxes, fats, oils, terpene hydrocarbons etc.
The three main steps in acquisition of a feedstock and converting it into useful
product are :
1. Source (lifetime methods and environmental impacts of extraction )
2. Separation of desired components from the waste or byproduct matter
3. Conversion of isolated feedstock material to desired product
Each of the above three steps have environmental effects and can benefit from the
application of the Principles of green chemistry
This Photo by Unknown Author is licensed under CC BY
Conventional synthesis of Adipic
acid from Cyclohexane
This Photo by Unknown Author is licensed under CC BY-NC
Green method for the synthesis of
Adipic acid from D-Glucose
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